Gas sampling system for reactive gas-solid mixtures

ABSTRACT

An apparatus and method for sampling gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extends in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

This is a division of application Ser. No. 07/235,358 filed 8/23/88, nowPat. No. 4,856,35,2.

BACKGROUND OF THE INVENTION FIELD OF THE INVENTION

The present invention relates in general to a system for sampling gasand, in particular, is directed to a system for sampling a gascontaining a reactive particulate solid phase such that essentially allof the solids are removed in such a manner that the gas phasecomposition is essentially unchanged. Thus, a representative gas sampleis obtained for determining its composition by a gas analyzer.

DESCRIPTION OF THE RELATED ART

Gas sampling systems are available from several vendors such as E.I.DuPont, etc., for use with gas analyzers. These systems, when designedfor dust-laden gases, clean the gas by filtration through a mesh screenor porous media. Where chemical reactions between the gas andparticulate matter potentially exist, these systems inadvertently allowthese chemical reactions to alter the chemical composition of the gassample by providing an intimate contact zone. Thus, the gas analysisequipment measures gas concentrations unrepresentative of the bulk gasstream.

Flue gas from fossil fuel fired boilers is one example of this kind ofgas-solid mixture. Recent concerns and awareness in our environment haveled to new efforts to refine our boiler technology with the removaland/or reduction of air pollutants such as particulates, sulfur oxides(SO_(x)), and oxides of nitrogen (NO_(x)).

During the combustion of fossil fuel, various combustion off-gases areproduced which contain a variety of contaminants such as sulfur dioxide,sulfur trioxide, and fly ash. U.S. Pat. No. 4,452,765, which is assignedto the assignee of the present invention, discloses a method forremoving sulfur oxides from a hot flue gas by introducing an alkalislurry. This patent is hereby incorporated by reference. The presentinvention finds particular utility in sampling the gas stream at variouspoints in that system to maintain air pollution emission controlstandards.

Accurate monitoring of the flue gas is required to be sure that methodslike this or newly developed ones are effective so that as a minimumthey improve the quality of the emission. A representative sample of thegas is necessary for an accurate analysis.

The prior art has recognized some of the problems of analyzingdust-laden gas samples. U.S. Pat. No. 4,485,684 issued to Weber, et aldiscloses an apparatus for extracting and analyzing dust-laden gassamples. The device employs a stilling chamber tapered downwards in theshape of a horizontal half-funnel in the direction of the flow of thegas. Flanges connect the stilling chamber to a gas sample extractionpipe or sample probe from an exhaust gas line. The gas sample extractionprobe of conventional construction extends coaxially in the connectingpipe. A conveying pipe which is connected to a three-way valve acts as aswitching valve and connects the gas probe to a conventional filter.From the filter the gas sample goes through a gas feed pump to a gasanalyzer. A time control device connected to the three-way valve permitscleaning with compressed air at specific intervals.

A different approach to this problem was used in U.S. Pat. No.3,106,843, issued to Luxl. This reference discloses an atmospheresampling probe for gas analyzers to obtain continuous flow of the samplestream. The clogging of the probe during extended periods of operationis prevented by utilizing steam which condenses about the solidparticles in the sample stream. Water is supplied to separate the steamby condensing it as well as washing the gas sample of corrosivematerials.

Both of these references only address the problem of the filtersclogging or plugging with dust. None of these prior art systemsrecognize the problem that chemical reactions occur between the gas andthe particulate material. Nor is the prior art directed to a gassampling system for sampling a gas containing a reactive solid phasesuch that the majority of the solids are removed in such a fashion thatthe gas phase composition is essentially unchanged and is therebyrepresentative of the gas sampled at the initial sampling point.

SUMMARY OF THE INVENTION

The present invention provides an apparatus and method for sampling agas containing a reactive solid phase flowing through a duct and forcommunicating a representative sample to a gas analyzer. The apparatuscomprises a sample probe sheath extending vertically into the top of agas duct. The sample probe sheath has an angular opening at one end withthe opening extending in the opposite direction of the gas flow. A gassampling probe partially extends into the sample probe sheath. Acalibration probe connected to a calibration gas line extends into thesample probe sheath with the calibration probe extending further in thesample probe sheath than the gas sampling probe. At least one filter isconnected between the gas sampling probe and a gas analyzer.

The calibration probe extends further in the sample probe sheath thanthe gas sampling probe for purging the sample probe sheath with thecalibration gas during calibration. Both the calibration and gassampling probes are sealed at the closed end of the sample probe sheath.The apparatus includes a means for maintaining the temperature rangewhich surrounds the apparatus to minimize gas-solids reactions.

Another aspect of the present invention is directed to a method forsampling a gas containing a reactive solid phase and flowing through aduct to communicate a representative sample to a gas analyzer. Themethod includes the steps of aspirating a gas containing a reactiveparticulate solid phase into a primary separation zone in a sample probesheath, and drawing a sample into a sample probe located within thesample probe sheath. Maintaining the temperature within a range whichminimizes gas-solids reactions provides for the continuousrepresentative monitoring of the gas concentration. Periodic calibrationof the gas analyzer is provided by the calibration probe whichdischarges a predetermined concentration of gas constituents into thesample probe sheath at a flow rate in excess of the gas sampling rate.

Advantageously, the gas sampling configuration of the present inventionallows continuous, representative monitoring of gas concentrations andeliminates damage or drift to instrumentation from solids. Easy accessto the filter assembly minimizes downtime when filter changes arerequired.

The various features of novelty characterized in the invention arepointed out with particularity in the claims annexed to and forming apart of this disclosure. For a better understanding of the invention,and the operating advantages obtained by its use, reference is made tothe accompanying drawings and descriptive matter in which the preferredembodiment of the invention is illustrated.

BRIEF DESCRIPTION OF THE DRAWING

In the drawings:

FIG. 1 is a schematic block diagram of a portion of a representativeboiler system where the present invention is employed to monitor fluegas emission, and

FIG. 2 is a cross-sectional illustration of the preferred embodiment ofthe present invention in place on a gas duct.

DESCRIPTION OF THE PREFERRED EMBODIMENT

Referring to FIG. 1, there is illustrated a schematic representation ofthe air pollution control components in a conventional boiler system.Hot flue gas derived from the combustion of fossil fuel is conveyed froma combustion zone, not shown but well known in the art, through conduit2 to spray drying reactor chamber 4. Steam or air supplied by a sourcenot shown is conveyed by conduit 6 to spray drying reactor chamber 4.The alkali slurry supplied by a system disclosed in U.S. Pat. No.4,452,765 is delivered to spray drying reactor chamber 4 by means ofconduit 8.

The hot flue gas is treated in the fashion as described in U.S. Pat. No.4,452,765. Settleable particulate matter is removed by gravity forcollection in ash hopper 10 where it is conveyed by conduit 12 forultimate disposal.

The flue gas exits the spray drying reactor chamber 4 passing through agas reheat zone 14 for gas reheat when required for corrosion control indry particle collection zone 16. The dry particle collection is achievedwith the use of an electrostatic precipitator, a fabric filter, or thelike. The treated gas leaves the dry particle collection zone 16 throughconduit 18 substantially free of particulate matter and sulfur oxides.The flue gas is then pumped through conduit 20 to an exhaust stack 22for atmospheric discharge.

Reacted alkali particles and fly ash that are collected in ash hoppers24 are conveyed by conduit 26 to reprocessing zone 28 for reprocessingand recycling.

Monitoring the flue gas such as in the gas reheat zone 14, and conduits18, 20 at several points in the system reveals the effectiveness of thepollution control technique. For purpose of this invention, the term"duct or gas duct" is meant to include the above-mentioned points in aboiler system.

With reference to FIG. 2, a gas-solid mixture normally travels through agas duct 30 with the arrow in duct 30 indicating the direction of flowof the gas-solid mixture. A sample probe sheath 32 extends into thesample gas duct 30. The sample probe sheath has an angular opening 34 atone end with the opening 34 being in the opposite direction of the gasflow as shown by the arrow in gas duct 30. An opening with a 45° angleis preferred. Other angles are usable with probably no significantconsequence. A 45° angle is easy to cut, i.e., it is a mitered corner.Alternate geometries can be envisioned such as a closed pipe with a slotopening on the downstream side. However, the angled cut is preferred forcleaning purposes.

The vertically orientated sample probe sheath 32 has a sufficient innerdiameter to allow for a primary separation of the particulate solidswhich accompany the gas sample. In a pilot test, a diameter of 21/2inches was suitable for a 12 inch gas duct. In the boiler industry,ducts of varying size are encountered and so the emphasis shifts tocompliance with the Environmental Protection Agency continuous emissionmonitoring standards (CEMS). The sample probe sheath 32 extends into agas duct 30 to a representative location of the gas stream. The sampleprobe sheath 32 is completely sealed from possible infiltration ofambient air at its opposite end 38.

A conventional gas sampling probe 36 passes through the sample probesheath end connection 38. The gas sampling probe draws a partiallyclean, i.e., reduced particulate concentration of gas-solid mixture fromthe primary separation zone which is defined as, a point between thesample probe sheath inlet 34 and the end of the gas sampling probe 36a.The distance from the end of the gas sampling probe 36a to the sampleprobe sheath inlet 34 may range conveniently from three to eight sampleprobe sheath inner diameters, but can be a greater distance if sampleresponse times are not critical to the application. A point midway inthe sample probe sheath 32 is preferred.

The calibration probe 40 passes through the sample probe sheath endconnection 38 for optional delivery of an appropriate calibration gas.One end of the calibration probe 40 is connected to a source forcalibration gas (not shown). The calibration line outlet 42 which has aplurality of small apertures discharges into the primary separationzone. A calibration gas at a sufficient volumetric flow rate to purgethis area of the sample probe sheath 32 is injected while a calibrationgas is drawn into the gas sample probe 36. The calibration gas flow ratemust be greater than the sample gas flow rate to insure that this probesheath 32 is flooded with calibration gas.

The gas sample probe 36 delivers the gas-solid mixture from the primaryseparation zone to the filter elements 44 through gas line 46. Thesefilters 44 contain media filters which remove a minimum of 99.99% of theentering solids having a diameter equal to or greater than 0.1 microns.

As shown in FIG. 2, two filters 44 are used in parallel to each other.Originally, this arrangement was intended to use one filter at a timewith the other as a spare. When it became necessary to change thatfilter, the operator would switch flow over to the spare filter by avalving arrangement 44a and then replace the used filter when the sparefilter became clogged. Due to the amount of time a filter lasts, it waslater found merely convenient to simply operate with both filters inparallel. Any number of filters or filter sizes in a suitablearrangement can be used.

In the preferred embodiment, the filters 44 are Balston® type BH filtersType 37/12. These filters have an inorganic binder and are recommendedfor sample filtrations above 300° F., to a maximum temperature of 900°F.

The filters 44 including line 46 along with the gas sampling probe 36and calibration probe 38 and the upper portion of the sample probesheath 32 are maintained within a temperature range to minimizegas-solids reactions (either above or below the gas flow temperature) bythe oven 48. These types of ovens which can maintain a temperature rangeabove or below the flow temperature are well known.

The common filter outlet of gas line 46 as it exits filters 44 isconnected to a heated hose or other suitable tube 50 to deliver thefiltered gas to a conventional gas analyzer 52.

For most applications, the material contacting the gas are made of somegrade of stainless steel.

The gas sampling apparatus described allows continuous, representativemonitoring of gas concentrations and eliminates damage or drift to theinstrumentation from particulate solids. Easy access to the multiplefilter assembly minimizes or eliminates downtime when filter changes ormaintenance are required.

The following are some example applications of the gas sampling systemof the present invention.

One application of this sampling system involves its use with dryscrubbers. In dry scrubbers an aqueous slurry of calcium hydroxide,(Ca(OH)₂, is sprayed into a hot flue gas (typically, about 300° F.)containing traces of sulfur dioxide, SO₂. The following reaction ensueswithin the dry scrubber:

    Ca(OH).sub.2 +SO.sub.2 →CaSO.sub.3.1/2H.sub.2 O+1/2H.sub.2 O (I)

Typically, an excess of slurry is sprayed into the flue gas such that asthe flue gas leaves the dry scrubber, moist particles of unreactedcalcium hydroxide slurry flow coincident with the flue gas. At thispoint the flue gas is typically below about 200° F. and the relativehumidity is above 10%. In a conventional sampling system, a smallportion of the flue gas would be extracted from the flue or duct andwould be directed to a filter where the calcium hydroxide solids wouldbe separated from the gas sample. A cake of solids would rapidlyaccumulate on the filter. The reaction noted above, (I), would continueto occur. Thus, any gas sample passing through the filter would nolonger contain a representative concentration of SO₂. The subjectinvention circumvents this problem in two ways. First, the method bywhich the flue gas is extracted, i.e., by requiring the flue gas to flowin reverse direction into the probe sheath causes an inertial separationof flue gas and slurry droplets. This serves to minimize (but noteliminate) the amount of solids which will reach and deposit on thefilter. Secondly, experience has shown that the above reaction proceedsat a negligible rate when the relative humidity of the flue gasapproaches zero. Therefore, by placing the external filter of thissubject invention in a zone where the temperature is maintained between250° F. and 350° F. this reaction can be minimized. As a result, the SO₂concentration is not diminished as it passes across a filter cake of dryCa(OH)₂.

Another benefit of the subject invention when compared to conventionalfilter based sampling systems is that frequent filter cleaning byvarious "blow back" procedures (as is usually used in commercialsampling systems) is not necessary. In-duct filters frequently requireblow back every twenty minutes or so in order to prevent pluggage by thefilter cake or to prevent significant sample degradation byaccumulations of reactive solids. The subject invention minimizes therate of accumulation of filter cake by the inertial separation step.That factor in combination with the temperature control which minimizesthe reactivity of the filter cakes allows operation even in very dirtyapplications for up to several weeks before filter replacement becomesnecessary. An added benefit of this fact is that media type filters canbe used in place of sintered ceramic or metal filters which are usedwith blow back systems. Media filters (usually fiber glass) are muchmore effective filters and operate generally at much lower pressure dropthan do the sintered type filters.

A second example of a system where the subject invention is applicableis in sampling flue gas in furnace sorbent injection applications.Typically, the reaction involved is represented by:

    CaO+SO.sub.2 +1/2O.sub.2 →CaSO.sub.4                (II)

This reaction is very rapid in the temperature range from about 1500° F.to about 2300° F. but diminishes to a negligible rate below about 700°F. Therefore, filtration at any temperature below about 700° F. shouldpresent no reaction problems via reaction (II). In principle, therefore,in-duct filters used in this temperature range should work adequately.However, because these in-duct filters must be cleaned by blow-back withcompressed air, that filter is periodically cooled by the relativelycold compressed air to temperatures well below 700° F. When thathappens, moisture can condense on the filter causing the deposits tobecome moist and therefore reactive via reaction (I). As in example oneabove, the subject invention avoids these problems by maintaining thefiltration step at a temperature of about 300° F. and by avoiding theneed for blow-back of the filter.

A third example of a system where this subject invention has been testedis on a wet scrubber utilizing a solution of sodium carbonate to reactwith SO₂ via:

    Na.sub.2 CO.sub.3 +SO.sub.2 →Na.sub.2 SO.sub.3 +CO.sub.2 (III)

The sampling constraints here are similar to the first example. However,the reactivity of sodium carbonate is greater than Ca(OH)₂ andtherefore, greater care must be taken in controlling the filtrationtemperature. By coincidence, 300° F. is the optimum temperature tofilter sodium carbonate from the sampled flue gas.

The foregoing examples are intended for illustrative purposes and arenot meant to limit the present invention only to these applications. Thegas sampling system of the present invention has utility in any systemwhere there exists a gas-solid mixture with the possible occurrence ofgas-solid reactions.

While a specific embodiment of the invention has been shown anddescribed in detail to illustrate the application of principles of theinvention, certain modifications and improvements will occur to thoseskilled in the art upon reading the foregoing description. It is thusunderstood that all such modifications and improvements has been deletedherein for the sake of conciseness and readability but are properly inthe scope of the following claims.

One example of such a modification would be to include a plurality offilters in parallel with valves directing the sampled gas to apredetermined filter or set of filters.

What is claimed is:
 1. A method for sampling a gas containing a reactiveparticulate solid phase flowing through a duct and for communicating arepresentative sample to a gas analyzer, comprising the stepsof:situating a vertically orientated sample probe sheath so that itextends into the sample gas duct, the sample probe sheath having anangular opening at one end with the opening in the opposite direction ofthe gas flow; establishing a primary separation zone by providing a gassampling probe partially extending into the sample probe sheath;situating a calibration probe which is connected to a calibration gasline to extend into the sample probe sheath substantially parallel tothe gas sampling probe, the calibration probe extending further in thesample probe sheath than the gas sampling probe to allow for purging thesample probe sheath with a calibration gas; aspirating the sample gascontaining a reactive particulate solid phase into the primaryseparation zone; drawing the sample into the sample probe; delivering arepresentative sample through at least two filters to the gas analyzer,each of the filters being outside of the gas sample duct connected inparallel with respect to each other between the gas sampling probe andthe gas analyzer with each of the filters further having a valve toallow for diverting sample gas flow for replacement of the filter; andmaintaining a temperature range around a part of the gas samplingapparatus for minimizing reactions between the gas and solids, themaintained part being the sample probe sheath, the calibration probe,and the gas sampling probe outside of the gas duct, and the filters. 2.A method according to claim 1, further comprising the step ofcalibrating the primary separation zone with a calibration gas prior tothe aspirating step.
 3. A method as recited in claim 1, wherein thesituating step includes a sample probe sheath with an angular opening ofabout 45°.